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71.
《Journal of Saudi Chemical Society》2021,25(9):101317
The novel palladium nanoparticles (Pd@POPs) were successfully prepared with controllable sizes and dispersity through the introduction of H2PdCl4 into urea-linked porous organic polymers (POPs) in an aqueous environment followed by reducing Pd(II) to Pd(0) by NaBH4. The newly prepared Pd@POPs were thoroughly characterized by FT-IR, ICP-AES, BET, XRD, SEM and TEM. Furthermore, the catalytic reactivities of this novel Pd@POPs were investigated via Heck, Suzuki-Miyaura cross-coupling reaction and nitroarene reduction, and they exhibited superior catalytic performances in all these three reactions, producing the corresponding products in up to quantitative yields. Additionally, the Pd@POPs had excellent recyclability in both Heck and Suzuki-Miyaura cross-coupling reactions with the repeating time up to four times and ten times, respectively, along with no obvious decrease of catalytic reactivities. 相似文献
72.
为了使用单细胞电感耦合等离子体质谱(SC-ICP-MS)方法准确测定单个细胞中的铬(Cr)、锰(Mn)、铁(Fe)、铜(Cu)和锌(Zn)等多种内源性金属元素,该文基于动态反应池(DRC)模式对目标分析物的反应气流量和极杆抑制参数q(RPq)进行了优化,并研究了进样速度、细胞密度、驻留时间等因素对SC-ICP-MS检测的影响。分别采用细胞悬液直接进样、使用超声波探头使细胞悬液中的细胞破碎后进样和使用浓硝酸消解细胞后进样的ICP-MS测定结果对SC-ICP-MS定量结果的准确性进行验证分析。实验结果表明,可采用超声波破碎细胞的ICP-MS测定结果评估SC-ICP-MS测定的单细胞内Zn和Cu含量的准确性,采用酸消解细胞的ICP-MS检测结果验证单细胞内Fe和Cr的含量。缺少细胞标准物质时对SC-ICP-MS方法定量结果进行多角度验证是必要的。研究表明,使用SC-ICP-MS法可以较好地进行单细胞元素相关分析。 相似文献
73.
《中国化学》2017,35(9):1366-1370
A new protocol for the NiCl2 ‐catalyzed cross‐electrophile coupling of aryl bromides with pyrimidin‐2‐yl tosylates to give the corresponding C2 ‐arylation pyrimidine derivatives has been developed. This study provides an improvement over previous methods by using pyrimidin‐2‐yl tosylates instead of halides as coupling partners that are stable and easily available. 相似文献
74.
Amina Kemmouche Hocine Ali-Khodja Fayrouz Bencharif-Madani Purificación López Mahía Xavier Querol 《International journal of environmental analytical chemistry》2017,97(12):1132-1150
When high mineral loads in atmospheric particulate matter (PM) are present, particular attention should be paid to the selection of appropriate acidic digestion protocols for wet chemical analysis. We report on a comparative study of elemental recovery yields from five different pre-analytical acid digestion procedures for mineral-rich urban background PM10 samples collected in the city of Constantine (Northeastern Algeria). Five reference materials (NIST 1633b, UPM 1648, NAT-7, SO-2 and SO-4) were also digested according to the same protocols. The selected acidic digestion/extraction procedures are widely used for PM chemical analysis and comprise P1 (HNO3/HF/HCl), P2 (HCl/HNO3), P3 (HCl/H2O2/HNO3), P4 (HNO3/HF/HClO4) and P5 (HNO3/H2O2); the latter assisted with microwave digestion. Elemental recovery yields were compared for major and trace elements typically determined in PM for source apportionment analysis and the results evidenced large differences. For most elements, the bulk extraction procedures (requiring the use of HF) allowed a full elemental recovery, particularly for elements that are associated with aluminium silicate species and oxides that are resistant to mild acid attack. In contrast, in the extraction protocols without HF low recovery yields were obtained for elements such as Al, Ti, Zr, Sc and other aluminium silicate-related elements in PM10 samples with high mineral dust load. We highlight that the European standard digestion method EN-14902:2005 should be applied specifically for the metals for which this method was developed, but caution should be taken when the analysis of other elements in PM is required, especially in urban areas where road and vehicle wear dust is likely to be a major component of ambient PM. When using wet chemistry analysis for PM source apportionment studies, we strongly recommend HF bulk dissolution of samples to ensure the reliability of the geochemical information when coupled with an appropriate analytical tool. 相似文献
75.
Lingyun GAO 《数学物理学报(B辑英文版)》2017,37(1):187-194
In this paper, we will mainly investigate entire solutions with finite order of two types of systems of differential-difference equations, and obtain some interesting results. It extends some results concerning complex differential (difference) equations to the systems of differential-difference equations. 相似文献
76.
Chuanzhong LI 《数学物理学报(B辑英文版)》2017,37(4):1151-1161
In this paper, we construct a new integrable equation called Mbius-Toda equation which is a generalization of q-Toda equation. Meanwhile its soliton solutions are constructed to show its integrable property. Further the Lax pairs of the Mbius-Toda equation and a whole integrable Mbius-Toda hierarchy are also constructed. To show the integrability, the bi-Hamiltonian structure and tau symmetry of the Mbius-Toda hierarchy are given and this leads to the existence of the tau function. 相似文献
77.
Mateusz B. Majka 《Stochastic Processes and their Applications》2017,127(12):4083-4125
We present a novel idea for a coupling of solutions of stochastic differential equations driven by Lévy noise, inspired by some results from the optimal transportation theory. Then we use this coupling to obtain exponential contractivity of the semigroups associated with these solutions with respect to an appropriately chosen Kantorovich distance. As a corollary, we obtain exponential convergence rates in the total variation and standard -Wasserstein distances. 相似文献
78.
选取了我国30个省市2006~2015年的面板数据,应用面板数据计量模型回归的方法,基于R语言对影响商品房价格的因素进行实证研究.首先,经过Hausman检验与F检验确定面板数据的模型为混合估计模型;模型可以通过十折交叉验证法、残差正太性的检验、Q-Q图检验、变量间共线性的检验;最后经过逐步回归分析,结果表明土地价格、商品房销售面积、居民可支配收入、人均国内总产值财政收入占地区生产总值比重、汇率这6个指标对商品房价格都有显著性的影响.其中,土地价格和居民可支配收入对商品房价格的影响最为突出. 相似文献
79.
Quantum reaction dynamics of C(1D) + HD → CH(CD) + D(H) on the ground state potential energy surface 下载免费PDF全文
We present accurate quantum dynamic calculations of the reaction C(1D) + HD on the latest version of the potential energy surface [Zhang et al., J. Chem. Phys. 140, 234301 (2014)]. Using a Chebyshev real wave packet method with full Coriolis coupling, we obtain the initial state‐specified ( ) reaction probabilities, integral cross sections, and rate constants. The resulting probabilities display oscillatory structures due to numerous long‐lived resonances supported by the deep potential well. The calculated rate constants and CD/CH product branching ratio at room temperature are in reasonably good agreement with the experimental measurements. 相似文献
80.
Global X2A′ potential energy surface of Li2H and quantum dynamics of H + Li2 (X1Σg+) → Li + LiH (X1Σ+) reaction 下载免费PDF全文
A global potential energy surface (PES) for the electronic ground state of Li2H system is constructed over a large configuration space. About 30 000 ab initio energy points have been calculated by MRCI‐F12 method with aug‐cc‐pVTZ basis set. The neural network method is applied to fit the PES and the root mean square error of the current PES is only 1.296 meV. The reaction dynamics of the title reaction has been carried out by employing time‐dependent wave packet approach with second order split operator on the new PES. The reaction probability, integral cross section and thermal rate constant are obtained from the dynamics calculation. In most of the collision energy regions, the integral cross sections are in well agreement with the results reported by Gao et al. The rate constant calculated from the new PES increases in the temperature range of present investigation. 相似文献